期刊
MACROMOLECULES
卷 46, 期 19, 页码 7696-7704出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma401311s
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资金
- UK Engineering and Physical Sciences Research Council (EPSRC) [EP/I004424/1]
- EPSRC [EP/F067496/1, EP/L000202/1, EP/H000925/1]
- EPSRC UK National Service for Computational Chemistry Software (NSCCS) at Imperial College London
- Royal Society
- Engineering and Physical Sciences Research Council [EP/K039687/1, EP/H000925/1, EP/F067496/1, EP/L000202/1, EP/I004424/1, EP/J003921/1] Funding Source: researchfish
- EPSRC [EP/L000202/1, EP/H000925/1, EP/J003921/1, EP/I004424/1, EP/K039687/1, EP/F067496/1] Funding Source: UKRI
The photophysical properties of insoluble porous pyrene networks, which are central to their function, differ strongly from those of analogous soluble linear and branched polymers and dendrimers. This can be rationalized by the presence of strained closed rings in the networks. A combined experimental and computational approach was used to obtain atomic scale insight into the structure of amorphous conjugated microporous polymers. The optical absorption and fluorescence spectra of a series of pyrene-based materials were compared with theoretical time-dependent density functional theory predictions for model clusters. Comparison of computation and experiment sheds light on the probable structural chromophores in the various materials.
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