期刊
MACROMOLECULES
卷 45, 期 10, 页码 4128-4133出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma3004899
关键词
-
资金
- Institute for Chemical Research, Kyoto University
- New Energy and Industrial Technology Development Organization (NEDO) of Japan
Polycondensation via direct arylation of tetrafluorobenzene or octafluorobiphenyl was investigated for the synthesis of pi-conjugated polymers consisting of fluorinated arylene units. The optimization of reaction conditions revealed that a combination of Pd(OAc)(2) and (PBu2Me)-Bu-t-HBF4 is the most efficient catalytic system for the polycondensation reactions. The polycondensation reactions produced four types of pi-conjugated polymers having low highest occupied molecular orbital (HOMO) levels due to the strong electron-withdrawing nature of the fluorine substituents. Owing to the low HOMO levels, the synthesized polymers served as an efficient hole-blocking layer (HBL) in OLEDs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据