期刊
MACROMOLECULES
卷 45, 期 4, 页码 1723-1736出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma201924h
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资金
- German Science Foundation (DFG) [TH 1104/4-1]
- National Science Foundation [CHE 0924435]
- American Chemical Society [49892-ND7]
- National Research Foundation of Korea
- Ministry of Education, Science and Technology [R31-10013]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0924435] Funding Source: National Science Foundation
Polymers featuring photolabile groups are the subject of intense research because they allow the alteration of polymer properties simply by irradiation. In particular, the o-nitrobenzyl group (o-NB) is utilized frequently in polymer and materials science. This Perspective pays particular attention to the increasing utilization of this chemical group in polymer chemistry. It covers the use of (i) o-NB-based cross-linkers for photodegradable hydrogels, (ii) o-NB side chain functionalization in (block) copolymers, (iii) o-NB side chain functionalization for thin film patterning, (iv) o-NB for self-assembled monolayers, (v) photocleavable block copolymers, and (vi) photocleavable bioconjugates. We conclude with an outlook on new research directions in this rapidly expanding area.
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