期刊
MACROMOLECULES
卷 45, 期 20, 页码 8438-8444出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma3016568
关键词
-
资金
- Office of Naval Research [00014-09-1-1125]
The influence of poly(tetramethylene oxide) (PTMO) soft segment length on the phase-separated microstructure, state of hydrogen-bonded associations, and molecular dynamics was investigated in polyureas polymerized from the bulk. For higher PTMO molecular weights (1000 and 650 g/mol) hard segments self-assemble into ribbon-like domains, while incorporation of a 250 g/mol soft segment leads to a predominately mixed segment material. The degree of microphase separation of the hard and soft segments, however, is rather incomplete for polymers synthesized from 1000 and 650 g/mol PTMO and decreases with decreasing soft segment molecular weight. Broadband dielectric relaxation spectroscopy reveals two segmental relaxations: a soft segment rich (alpha) and slow segmental (alpha(2)) process. When the molecular weight is reduced from 1000 to 650 g/mol the mobility of these processes is reduced, consistent with findings from differential scanning calorimetry and dynamic mechanical analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据