期刊
MACROMOLECULES
卷 45, 期 21, 页码 8796-8804出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma300957d
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资金
- University of Massachusetts Lowell, USA
- Scientific Council of the RAS
A principal possibility to synthetically control the distance between the branching nodes of poly(propenylsilane) dendrimer molecules has been shown This was achieved by performing a relatively simple procedure-adding to the classic dendrimer building process a stage involving a bifunctional reagent: dimethylchlorosilane. As a result two series of carbosilane dendrimers with doubled node-to-node distance, from previously achieved, were synthesized which. differed by the distribution pattern of terminal allyl groups. A sixth generation dendrimer with varied node-to-node distance in the core and periphery had been synthesized. These compounds were isolated by preparative LC and were characterized by H-1, C-13, and Si-29 NMR, Mass Spectroscopy, and GPC. Their characteristic viscosities and hydrodynamic diameters were identified. A comparative analysis of properties of synthesized dendrimers and their counterparts from half the distance between the branch nodes had been performed.
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