期刊
MACROMOLECULES
卷 44, 期 16, 页码 6532-6538出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma2009854
关键词
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资金
- Agence Nationale de la Recherche [ANR-09-JCJC-0032-01]
- EPRSC
The aqueous solution properties of amphiphilic tetrathiafulvalene (TTF) end-functionalized poly(N-isopropylacrylamide) (PNIPAM) derivative 1 have been studied. Fluorescence spectroscopy, dynamic light scattering (DLS) and differential scanning calorimetry (Nano-DSC) were used to monitor the temperature-induced micellization and showed that 1 underwent two successive phase transitions corresponding to unimer-to-micelle and lower critical solution temperature (LCST) transitions, respectively. We have investigated the complexation properties of the TTF unit toward cyclobis(paraquat-p-phenylene) (CBPQT(4+)) or the randomly methylated beta-cyclodextrin (RAMEB) to manipulate the amphiphilicity of 1 and to control the unimer-to-micelle phase transition by forming pseudorotaxane-like architectures. For the RAMEB complex with 1, the addition of a competitive guest such as 1-adamantanol resulted in the restoration of amphiphilicity of polymer 1 and consequently the reformation of micelles.
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