期刊
MACROMOLECULES
卷 44, 期 12, 页码 4596-4599出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma2008628
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资金
- BASF Schweiz AG, Basle, Switzerland
pi-Conjugated monomers and polymers containing benzodifuranone units in the main chain were prepared. Polymers were obtained using palladium-catalyzed Suzuki and Stifle polycondensation reactions of dibromo-substituted benzodifuranone derivatives with either dihexylfluorene diboronester or bis(trimethylstannyl)thiophene. The optical and electronic properties were investigated using UV/vis absorption spectroscopy and cyclic voltammetry. It was found that the polymers show very broad absorption bands with a high extinction coefficient up to 32500 L mol(-1) cm(-1). The polymers also show reversible redox behavior, giving small HOMO-LUMO gaps up to 1.30 eV with strong donor-acceptor character.
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