期刊
MACROMOLECULES
卷 43, 期 19, 页码 8185-8190出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma1014758
关键词
-
资金
- Materials and Manufacturing Directorate
- Air Force Office of Scientific Research
We report on the influence of cross-link density of azobenzene-containing liquid crystal polymer networks (azo-LCNs) on the thermomechanical properties and the laser-directed bending of cantilevers consisting of these materials. Cross-link density of azo-LCN was increased by adjusting the length of photocuring from 1 to 120 min. The storage modulus (E'), loss modulus (E ''), and glass transition temperature (T-g) of the azo-LCNs increase with cross-link density. Increasing the cross-link density of the polydomain azo-LCN reduces the magnitude of the bending angle of the cantilevers. The relationship between the thermomechanical and photomechanical properties oldie polydomain azo-LCN reported here is further elucidated in the examination of laser-directed bending over a wide range of temperature. The temperature dependence of the equilibrium photodriven bending angle is shown to be strongly related to the temperature dependence of the storage modulus for a given azo-LCN sample. Normalizing the temperature dependence of the photomechanical response of the azo-LCN cantilevers by the T-g provides a master curve that can be used to tailor the photomechanical response.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据