期刊
MACROMOLECULES
卷 43, 期 6, 页码 2840-2845出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma902789g
关键词
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资金
- National Natural Science Fund of China [20974018, 20971021]
- Ministry of Education of China [20070255012]
- Shanghai Leading Academic Discipline Project [13603]
- Open Project of the State Key Laboratory of Crystal Materials [KF0809]
- Program of Introducing Talents of Discipline to Universities [111-2-04]
- China Postdoctoral Science Foundation [20080440563, 200902193]
A series of new molecular hybrids with stilbene chromophore (H1-H4) are prepared by hydrosilylation of octahydridosilsesquioxane (T-8(H)). All these stilbene-containing hybrid materials arc soluble in common organic solvents, such as chloroform, toluene, THF, and 1,2-dichloroethane, and possess good film-forming properties. Their structures and properties are characterized and evaluated by FT-IR, NMR, UV, PL, TGA, DSC, nonlinear optical (NLO), and optical limiting (OL) analyses. The results show that the thermal decomposition temperatures (T-d, 5 mass % loss) of the hybrids are 20-60 degrees C greater than their corresponding stilbene monomers, and the hybrids show obvious nonlinear absorption (beta up to 2.56 x 10(-11) m/W) and optical limiting properties. The larger excited-state absorption cross sections than corresponding ground-state absorption cross sections of the hybrids indicate that reverse saturable absorption is a major mechanism responsible for the optical limiting of the hybrids.
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