期刊
MACROMOLECULES
卷 42, 期 22, 页码 8870-8874出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma901765j
关键词
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资金
- National Natural Science Foundation of China [50515204, 50832001, 50902057]
- Ministry of Education, Science and Technology Development Programmer of Jilin Province [200801830025]
- Jilin University, China [211, 985]
- [20090703]
Two poly(vinylidene fluoride)(PVDF)/carbon nanotube (CNT) composites are prepared by solution sonication and mechanical mixture approaches. It is found that alpha-phase coexists with beta-phase in the composite prepared by sonicating the PVDF/CNT mixture solution, while no beta-phase can be observed in the composite prepared from the mechanical mixture route. With the help of the density functional theory calculations, it is explained that a large amount of energy is required for transforming transgauche-trans-gauche' (TGTG') into trans-trans (TT) conformations and the TT molecular chain can be bound on the CNT surface tightly. The emergence of beta-phases is independent of zigzag carbon atoms on the CNT surface. The formation mechanism of beta-phase is proposed based on the theoretical calculations and experimental results.
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