期刊
MACROMOLECULES
卷 42, 期 13, 页码 4449-4455出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma9006494
关键词
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资金
- NSF [DMR-0644727]
The synthesis ora new bisfuranyl monomer, 2,7-bis(2-furanyl)-1,6-methano[10]annulene, is presented. Its properties and those of its polymer, synthesized via electropolymerization, are compared to those of the known furan-arene-furan monomers and their respective polymers. Investigation using UV-vis spectroscopy, cyclic voltammetry, and spectroelectrochemistry indicated that the 1,6-methano[101 annulene copolymer has properties rivaling those of the copolymers containing traditional aromatic cores. These results are rationalized in conjunction with DFT calculations, and they further the premise that 1,6-methano[10]annulene can be viewed as a viable building block for advanced pi-conjugated electronic materials.
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