期刊
MACROMOLECULES
卷 42, 期 22, 页码 8697-8701出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma9018334
关键词
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资金
- Natural Science Foundation of China [50903060]
- Natural Science Foundation of Jiangsu Province [BK2007547]
- Program of Innovative Research Team of Soochow University
- Jiangsu Province
The phenylphosphinic acid-functionalized microspheres were successfully prepared by one-pot emulsion polymerization of styrene/divinylbenzene with a functional macromolecular reversible addition-fragmentation chain transfer (RAFT) agent, poly(3-[2-(zicryloyloxy)ethoxy]-3-oxopropyl(phenyl)phosphinic acid)-block-polystyrene (P(AOPA)-b-PSt), as an amphiphilic emulsifier. The monodisperse microspheres were obtained with about 300 nm of the diameters and the clear core-shell structures, while phenylphosphinic acid groups were introduced into the shell via the RAFT process. The functionalized microspheres show high ability to coordinate with Cu2+ or Fe3+.
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