期刊
MACROMOLECULES
卷 42, 期 9, 页码 3316-3325出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma802467j
关键词
-
资金
- Marie Curie program [HPMT-CT-2001-00227]
- Ministerio de Educacion y Ciencia of Spain [MAT 2003-01963, CTQ 2006-03412/PPQ]
- European Union [IP 011844-2]
- Gobierno Vasco
A cationic macromonomer, 2-methacryloylethylhexadecyldimethylammonium bromide MA16, and a cationic macroinitiator, cationic acrylic/styrene oligomer end-capped with a nitroxide, were used to modify pristine Na-MMT, to enhance compatibility between the clay platelets and the host acrylic polymer matrix in waterborne nanocomposites. Both cationic species were successfully exchanged in the montmorillonite. The organically modified clays were used for the synthesis of acrylic (MMA/BA)/clay waterborne nanocomposites by miniemulsion polymerization. The 30% solids containing latexes were stable and coagulum free and presented better mechanical, thermal and barrier properties than the pristine acrylic copolymer.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据