期刊
MACROMOLECULES
卷 41, 期 15, 页码 5577-5581出版社
AMER CHEMICAL SOC
DOI: 10.1021/ma801137r
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资金
- Engineering and Physical Sciences Research Council [GR/S25845/02, GR/S25845/01] Funding Source: researchfish
We report the synthesis of water-soluble cationic branched copolymers by quaternization of near-monodisperse poly [2-dimethylamino)ethyl methacrylate] chains using bis(2-iodoethoxy)ethane. This model system is very useful for exploring the relative propensities for intermolecular branching and intramolecular cyclization. At polymer concentrations higher than the critical overlap concentration (c*), intermolecular branching is preferred over intramolecular cyclization; however, below c*, intramolecular cyclization is much more likely than intermolecular branching. These results allow some rationalization of the apparently contradictory literature data on branched copolymers prepared by living radical copolymerizations.
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