期刊
MACROMOLECULAR RESEARCH
卷 21, 期 5, 页码 484-492出版社
POLYMER SOC KOREA
DOI: 10.1007/s13233-013-1053-2
关键词
fuel cells; proton exchange membranes; polyimides; sulfonation; stability
资金
- National Natural Science Foundation of China [50973040]
- Science and Technology Development Plan of Jilin Province, China [20100706]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry [504 3C1116801412]
- Industrial Technology Research and Development Funds of Jilin Province [2011004-1]
Two -SO3H containing diamine monomers, 2,5-bis(4-amino-2-trifluoromethylphenoxy)benzenesulfonic acid and 2,5-bis(4-aminophenoxy)benzenesulfonic acid were successfully synthesized through a typical aromatic nucleophilic substitution reaction followed by a reduction reaction, respectively. Derived from the diamine monomers, two series of sulfonated naphthalic polyimides (polynaphthalimides) containing ether and ketone linkages were synthesized through a one pot polymerization reaction. Some properties including thermal stability, mechanical properties, water uptake, swelling dimensional ratio, methanol permeability, and proton conductivity were thoroughly investigated. Some exhibited attractive properties as proton exchange membranes. It was found that the fluorinated series (CF3-SPI-X) exhibited higher dimensional stability and lower methanol permeability in comparison with non-fluorinated ones (SPI-X) at the same -SO3H group content.
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