4.3 Article

Effect of 3rd Monomer Addition on Styrene/Styryl-Polyhedral Oligomeric Silsesquioxane (POSS) Copolymerization

期刊

MACROMOLECULAR RESEARCH
卷 17, 期 5, 页码 352-+

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POLYMER SOC KOREA
DOI: 10.1007/BF03218874

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  1. Basic Research Program of the Korea Science and Engineering Foundation [R01-2004-000-10563-0]
  2. National Research Foundation of Korea [R01-2004-000-10563-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The copolymerization of St and St-POSS with and without 4-methylstyrene as the 3(rd) monomer had been studied in detail for Cp*TiCl3 catalyst. With the addition of 3(rd) monomer, an increased catalytic activity was observed and the St-POSS incorporation was also enhanced. The T-g of copolymers increased with increasing 3(rd) monomer content. With the incorporation of 3(rd) monomer, the thermal stability of St/St-POSS was improved.

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