期刊
MACROMOLECULAR REACTION ENGINEERING
卷 8, 期 10, 页码 706-722出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mren.201400013
关键词
copolymerization; crosslinking; monoliths; polymer networks; RAFT polymerization
资金
- Consejo Nacional de Ciencia y Tecnologia (CONACYT, Mexico)
The synthesis of monoliths by reversible addition-fragmentation chain transfer (RAFT) copolymerization of styrene and divinylbenzene (DVB) at high-crosslinker content is studied using the recently reported multifunctional polymer molecule approach. The agreement between model predictions, incorporating diffusion-control, and experimental data from CSIRO is good for all cases analyzed. This includes examples with high-crosslinker concentrations, which cause deviation from some of the simplifying assumptions imposed in the model.
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