期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 35, 期 6, 页码 666-671出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201300865
关键词
functionalization of polymers; modification; phthalate; plasticizer; poly(vinyl chloride) PVC
资金
- NSF [CHE-1057927]
Copper-free azide-alkyne click chemistry is utilized to covalently modify polyvinyl chloride (PVC). Phthalate plasticizer mimics di(2-ethylhexyl)-1H-triazole-4,5 dicarboxylate (DEHT), di(n-butyl)-1H-1,2,3-triazole-4,5-dicarboxylate (DBT), and dimethyl-1H-triazole-4,5-dicarboxylate (DMT) are covalently attached to PVC. DEHT, DBT, and DMT have similar chemical structures to traditional plasticizers di(2-ethylhexyl) phthalate (DEHP), di(n-butyl) phthalate (DBP), and dimethyl phthalate (DMP), but pose no danger of leaching from the polymer matrix and forming small endocrine disrupting chemicals. The synthesis of these covalent plasticizers is expected to be scalable, providing a viable alternative to the use of phthalates, thus mitigating dangers to human health and the environment.
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