期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 32, 期 12, 页码 859-869出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100162
关键词
epoxy anchoring layer; grafting to; polymer brush; surfaces; synthesis
资金
- National Science Foundation [CBET-0756457, CMMI-0825773, CMMI-082606, DMR-0602528, EEC-9731680]
- Sigma-Aldrich
- Department of Commerce through the National Textile Center [M01-CL03, C05-CL06]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [0756457] Funding Source: National Science Foundation
This paper focuses on the attachment of densely grafted polymer layers (polymer brushes) to various inorganic and polymeric substrates by the grafting to method. A brief overview of synthesis of polymer brushes by the method is first provided, with emphasis on chemical approaches to polymer attachment. The second part of the paper covers the synthesis of polymer layers via a recently developed macromolecular anchoring layer approach. Several examples of application of the grafting technique are presented for generation of hydrophobic, hydrophilic, gradient, and switchable surfaces.
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