期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 32, 期 11, 页码 807-812出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100159
关键词
diblock copolymer; electrospray ionization mass spectrometry (SEC/ESI-MS); ortho-quinodimethanes; photoconjugation; photo Diels-Alder
资金
- Karlsruhe Institute of Technology (KIT)
- German Research Council (DFG)
- Ministry of Science and Arts of the state of Baden-Wurttemberg
- Landesgraduiertenforderung Baden-Wurttemberg
Shining a light on click chemistry: The use of UV-radiation as trigger signal provides a facile means to obtain spatial and temporal control over polymer conjugation reactions in addition to providing a further means of achieving orthogonality in click transformations. In the current contribution, UV-radiation was employed to induce a highly efficient Diels-Alder conjugation of polymeric building blocks via the photo-induced in situ formation of highly reactive cis-dienes from a 2-methylbenzophenone precursor.
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