期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 32, 期 15, 页码 1123-1143出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100127
关键词
disulfide; end-group; functionalization of polymers; reversible addition fragmentation chain transfer (RAFT); thiol
资金
- Australian Research Council (ARC) [DP1092640, DP110104251]
- Federation Fellowship
- Australian Postdoctoral Fellowship
- Australian Research Council [DP1092640] Funding Source: Australian Research Council
Reversible addition fragmentation chain transfer (RAFT) polymerization is one of the most extensively studied reversible deactivation radical polymerization methods for the production end-group can easily be of well-defined polymers. After polymerization, the RAFT agent converted into a thiol, opening manifold opportunities for thiol modification reactions. This review is focused both on the introduction of functional end-groups using well-established methods, such as thiol-ene chemistry, as well as on creating bio-cleavable disulfide linkages via disulfide exchange reactions. We demonstrate that thiol modification is a highly attractive and efficient chemistry for modifying RAFT polymers.
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