期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 32, 期 18, 页码 1484-1489出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201100271
关键词
kinetics (polym.); poly(2-oxazoline)s; renewable resources; thiol-ene
资金
- Dutch Polymer Institute (DPI, Technology area HTE)
- Thuringer Kultusministerium [B715-07011, B515-07008]
- Landesgraduiertenfoerderung Thueringen
The bulk polymerization of 2-(dec-9-enyl)-2-oxazoline (DecEnOx), a fatty acid-based monomer for the cationic ring-opening polymerization, is reported. Furthermore, under optimal conditions, namely microwave heating at 100 degrees C, the bulk copolymerization with 2-ethyl-2-oxazoline yielded well-defined copolymers. Due to its pendant alkene groups DecEnOx-based polymers possess the potential to be modified in efficient thiol-ene reactions. The functionalization with thiols, e. g., dodecanethiol and 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glycopyranose in green'' solvents is demonstrated.
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