期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 31, 期 9-10, 页码 834-839出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900794
关键词
alkyne hydrosilylation; fluorescence; hyperbranched polymers; sensors; synthesis
资金
- Research Grants Council of Hong Kong [J-BB6K, 604509, 601608]
- National Science Foundation of China [20974028]
- University Grants Committee of Hong Kong [AoE/P-03/08]
- Cao Guangbiao Foundation of Zhejiang University
A silicon-containing hyperbranched polymer (hb-P1/2) with sigma*-pi* conjugation was prepared in a good yield and high molecular weight by rhodium-catalyzed alkyne polyhydrosilylation of 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene (1) with tris(4-dimethylsilylphenyl)amine (2). The polymer was thermally stable, losing merely 5% of its weight when heated to 445 C. Whereas hb-P1/2 was weakly luminescent when molecularly dissolved, it became highly emissive when supramolecularly aggregated, showing an aggregation-induced emission (ATE) phenomenon. A superamplification effect was observed when the ATE nanoaggregates were used as fluorescent chemosensor for explosive detection: the quenching efficiency was greatly increased in a nonlinear fashion with increasing quencher concentration.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据