期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 31, 期 9-10, 页码 856-860出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200900875
关键词
coordination polymers; MEPP; nanocubes; polymerization; Prussian blue
资金
- Engineering and Physical Sciences Research Council, UK (EPSRC)
Miniemulsion periphery polymerization (MEPP) has been used for the synthesis of Prussian blue (PB) nanocubes. Pentacyano ferrate functionalized surfactant in combination with a co-surfactant containing 4-(dimethylamino)-pyridine (DMAP) or OH end groups in lieu of ferrate functionality (EPE-DMAP or EPE-OH) were used to prepare a miniemulsion system comprising 20 wt.-% toluene and 0.5 wt.-% total surfactant. On addition of Fe3+ to the miniemulsion, metal coordination polymerization occurred with nanocubes generated when the ratio of EPE-Fe:EPE-DMAP (or EPE-OH) was 60:40 (w/w). The resulting nanocubes are apparently amorphous. Particles with irregular shape have been observed on reacting EPE-Fe and Fe3+ directly in water, thus suggesting that confinement of the polymerization field on the periphery of the miniemulsion droplets is a primary factor in the formation of cubic structures.
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