期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 30, 期 13, 页码 1043-1057出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200800720
关键词
living polymerization; nitroxide-mediated polymerization; polymer brushes; radical polymerization; surface-initiated polymerization
资金
- NRW Graduate School of Chemistry
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft [SFB 424]
This review article describes the preparation of polymer brushes by nitroxide-mediated radical polymerization using either the 'grafting to' or the 'grafting from' approach. The use of TEMPO as a classical initiator is intensively described. More sophisticated nitroxides are also included in the discussion. Brush formation on flat surfaces such as wafers and also on particles is reported. Finally, some applications of polymer brushes are presented.
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