期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 298, 期 1, 页码 53-66出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201100390
关键词
adhesives; crosslinking; miniemulsion polymerization; Monte Carlo simulation; structure-property relations
资金
- EU
- Diputacion Foral de Gipuzkoa, Basque Government [GV IT373-10, S-PE10UN25]
- Ministerio de Ciencia e Innovacion (MICINN) [CTQ2011-25572]
- Basque Government (Ikertzaileak Prestatzeko eta Hobetzeko Beken Programak'')
The effects of the CTA concentration on polymerization kinetics, polymer microstructure, particle morphology, and adhesive performance of waterborne hybrid PSAs prepared by simultaneous free-radical and addition miniemulsion polymerizations are studied. The development of the microstructure is shown to differ from waterborne acrylic PSAs obtained by free-radical polymerization because of the contribution of the addition reaction, which in turn causes marked differences in the adhesive performance of the final films. A computer simulation is developed to obtain detailed information about the microstructure of PU/acrylic hybrids and to correlate the microstructure with the final adhesive properties.
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