4.5 Article

Poly(propylene)/Carbon Nanofiber Nanocomposites: Ex Situ Solvent-Assisted Preparation and Analysis of Electrical and Electronic Properties

期刊

MACROMOLECULAR MATERIALS AND ENGINEERING
卷 296, 期 5, 页码 434-443

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201000341

关键词

carbon nanofibers; conductivity; nanocomposites; poly(propylene); rheological behavior

资金

  1. Lamar University
  2. Texas State University San Marcos

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CNF-reinforced PP nanocomposites were fabricated from CNFs dispersed in a boiling PP/xylene solution. Their thermal properties were characterized by TGA and DSC and shown to exhibit improved thermal stability and higher crystallinity. They were further processed into thin films by compression molding. The electrical conductivity and dielectric property of the PP/CNF nanocomposite thin films were studied. Both electric conductivity and real permittivity increased with increasing fiber loading. Electrical conductivity percolation is observed between 3.0 and 5.0 wt.-% fiber loading. The rheological behavior of the nanocomposite melts were also investigated. It was found that a small fiber concentration affects the modulus and viscosity of PP melt significantly.

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