期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 214, 期 16, 页码 1806-1816出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201300300
关键词
cationic polymerization; crosslinking; irradiation; photopolymerization; ring-opening polymerization
The cyclic azodioxide, 1,4,4-trimethyl-2,3-diazabicyclo[3.2.2]non-2-ene 2,3-dioxide (5), displays the unique ability to function as a thermally reversible inhibitor for the UV-induced photoinitiated cationic polymerizations of epoxide and vinyl ether monomers. At room temperature and below, the photopolymerizations are suppressed due to the capture of photogenerated initiating protons by the cis-azodioxide group, which is both basic and serves as a bidentate coordinating group. However, at higher temperatures, the azodioxide group reverts to its ring-opened dinitroso isomer and, as a consequence, loses its ability to coordinate to protons. Protons released during this process subsequently initiate the cationic polymerizations of the monomers. Reversible inhibitors such as 5 have several potential applications such as in the design of one-component photoactivatable structural and assembly adhesives and in composites.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据