期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 213, 期 23, 页码 2492-2497出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201200329
关键词
bioinspiration; conducting polymers; functionalization of polymers; superhydrophobicity; surfaces
The tuning of the surface morphology is crucial in the development of superhydrophobic surfaces with various wetting properties. Here, we report the synthesis and electrodeposition of poly(3,4-ethylenedioxypyrrole) (PEDOP) derivatives containing hydrocarbon chains (ethyl to tetradecyl). Surprisingly, the alkyl chain length has a very important influence on the surface morphology and as a consequence on the water-repellency properties. The amount of the nanoporosity and the water-repellency properties can be controlled with alkyl chain length. Moreover, it seems the presence of surface nanoporosity is in correlation with the steric hindrances induced by the alkyl chains during the electrodeposition. This paper uses bioinspired approaches (fluorocarbon free) to reach superhydrophobic surfaces.
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