期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 213, 期 8, 页码 847-857出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201100671
关键词
laponite; MALDI-TOF MS; poly(butyl acrylate); polymer; clay nanocomposites
资金
- Mpact Paper
- Stellenbosch University
Polymer/clay hybrid materials are synthesised by grafting polymer chains from the surface of Laponite clay via surface-initiated RAFT polymerisation of butyl acrylate. The grafted polymer chains are analysed directly from the clay using MALDI-TOF MS. The polymer-grafted clay particles are analysed regarding their oligomer distribution using a matrix of dihydroxy-9,10-dihydroanthracen-9-one (dithranol) without the addition of a cationising salt. The end-group structures of the free and grafted polymers are also studied. The work presented here expands the application bracket for MALDI-TOF MS as it shows that the analysis of polymers attached to a solid surface via electrostatic interactions is possible without detaching them. Complimentary results from SEC and NMR are also presented.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据