期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 212, 期 15, 页码 1545-1551出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201100182
关键词
cyclo-olefins; isomerization polymerization; late transition metal catalysts; non-conjugated dienes; stereoselective polymerization
资金
- Ministry of Education, Science, Sports and Culture, Japan [22685012]
- Grants-in-Aid for Scientific Research [22685012] Funding Source: KAKEN
Pd complexes with diimine ligands promote polymerization of cyclopentenes, 1,6-dienes, and 1,6,11-trienes to afford polymers having 1,2- or 1,3-five-membered ring in every repeating unit. The Pd complexes with C-2 symmetrical structure catalyze the polymerization reactions to produce polymers with high stereoselectivity. Some of the obtained polymers show characteristic properties such as thermoreversible gelation and liquid crystal formation. Ni complexes bring about the cyclopolymerization of the dienes to afford polymers containing five- and/or six-membered rings in controlled stereochemistry.
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