4.4 Article

Films of Highly Disperse Electrodeposited Poly(N-vinylcarbazole)-Graphene Oxide Nanocomposites

期刊

MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 212, 期 21, 页码 2371-2377

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201100334

关键词

electrodeposition; graphene oxide; polymer nanocomposites; poly(N-vinylcarbazole) (PVK); thin films

资金

  1. National Science Foundation [CBET-0854979, DMR-10-06776]
  2. Texas NHARP [01846]
  3. Robert A. Welch Foundation [E-1551]

向作者/读者索取更多资源

The electrodeposition of polymer nanocomposite thin films of PVK-GO is demonstrated. Highly exfoliated and stable graphene oxide (GO) solutions are prepared by incorporating poly(N-vinylcarbazole) (PVK) through mixing. Enhanced stability up to 30 d is observed in both aqueous and organic solvents. TGA, XRD, FTIR, and UV-vis measurements confirm nanocomposite formation. CV enables electrodeposition of the films. The presence of GO on the PVK-GO surface is confirmed by the appearance of the C=O and OH stretching vibrations, attributed to the carboxylic and hydroxyl groups of GO. AFM measurements show homogeneous and well-defined film morphology.

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