期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 211, 期 13, 页码 1482-1487出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200900523
关键词
atom-transfer radical polymerization (ATRP); block copolymers; polysiloxanes; polystyrene (PS); reversible addition/fragmentation chain transfer (RAFT)
资金
- Bausch Lomb
- Center for Advanced Materials Processing (CAMP) at Clarkson University, a New York Center for Advanced Technology
Amphiphilic ABCBA pentablock copolymers based on PVP, PS, and PDMS were synthesized using a combination of ATRP and RAFT polymerizations. The PVP-block-PS-block-PDMS-block-PS-block-PVP pentablock copolymer was characterized using a variety of chromatography and spectroscopic methods which showed that a high degree of end group and molecular weight control can be achieved. Preliminary analysis of the aqueous solution behavior of the pentablock copolymer showed that it self-assembles in water in order to shield the PDMS and PS segments from the water.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据