期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 211, 期 15, 页码 1712-1721出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201000117
关键词
crosslinking; elastomers; gels; polyurea; sol-gel
A series of elastomers based on polyurea chemistry is synthesized by crosslinking amino-terminated polyethers with a triisocyanate using an appropriate solvent, which slowed down the reactivity of the amino groups. Control of the reactivity allows the shaping of the material, and films of defined thickness can be achieved for mechanical testing. The strength of the final network can be tuned by the crosslinking density of the network chemical constitution. The resulting materials show a good thermal stability and promising mechanical enhancement.
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