期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 211, 期 17, 页码 1847-1856出版社
WILEY-BLACKWELL
DOI: 10.1002/macp.201000151
关键词
difunctional initiators; photocleavable block copolymers; self-assembly; stimuli-responsive polymersomes
资金
- Swiss National Science Foundation
- NCCR Nanosciences
- Swiss Nanoinstitute
The synthesis of a novel amphiphilic block copolymer containing a photodegradable linker as a junction point between hydrophilic and hydrophobic chains is presented. PmCL-ONB-PAA block copolymers were synthesized via a combination of ROP and ATRP from a difunctional photoresponsive initiator (ONB). The copolymers are biodegradable and biocompatible, they can self-assemble into different structures, including micelles and vesicles which are photoresponsive. When polymer solutions were exposed to UV we observed significant changes in size and number of particles. We are currently investigating the promising potential of this system as photosensitive nanocarrier.
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