期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 211, 期 22, 页码 2425-2433出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201000257
关键词
cellulose; electrochemistry; LB films; structure-property relations; supramolecular structures
资金
- Ministry of Education, Science, and Culture of Japan [17380107]
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [17380107] Funding Source: KAKEN
Role-sharing functionalized cellulose derivatives having Mg, Zn, Cu, and Pd porphyrins are used for photocurrent generation system fabricated by the LB technique, mimicking the array of natural photosynthetic light-harvesting systems. These polymers exhibited different absorption and redox properties in solution depending on the central metal ions. On visible light illumination, the LB film generated anodic photocurrent in the order of Pd > free base > Zn > Cu > Mg. By inserting Pd ion, using myristoyl group, and adjusting the DS, the photocurrent quantum yield was 6.9 times as great as that of conventional porphyrin cellulose. These findings may provide opportunities for the design of a new class of organic solar cells, based on cellulose molecular characteristics.
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