期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 210, 期 18, 页码 1536-1543出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200900094
关键词
amantadine; atom transfer radical polymerization (ATRP); initiators; MMA; thermogravimetric analysis (TGA)
资金
- Department of Science & Technology (DST), New Delhi
- IIT, Kharagpur
This investigation reports the preparation of poly(methyl methacrylate)s bearing amino adamantyl functionality as the end-group via atom transfer radical polymerization (ATRP) using amino-adamantyl isobutyryl bromide (Am-AdiBr) as initiator. The rate of polymerization was slow compared to that of ATRP of methyl methacrylate (MMA) using conventional ATRP initiator. This may be due to the coordination between amine group and copper catalyst. All the polymers had well-defined end group. The presence of end group was confirmed by H-1 NMR, MALDI-TOF-MS analysis, and block copolymerization experiments using PMMA bearing -Br end group as the macroinitiator. The thermal properties of the polymer were investigated by TGA and DSC analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据