期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 209, 期 3, 页码 279-289出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.200700416
关键词
crosslinking; latices; model reaction; TMI
The mechanism of TMI-induced crosslinking was studied using model reactions in a mixture of TMI water and acetic acid. The hydrolysis of TMI was slow at room temperature, but could be enhanced by the incorporation of carboxylic acid groups. The formation of amide linkages via condensation between TMI and carboxylic acid groups did occur at room temperature, but was very slow. The crosslinking of a fully crosslinked latex film was also studied using a new type of latex. The degree of crosslinking of the core-crosslinked latex films was lower than theoretical values and the mechanical properties were poor, which was ascribed to insufficient interfacial crosslinking. [GRAPHICS]
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据