期刊
LANGMUIR
卷 30, 期 23, 页码 6748-6755出版社
AMER CHEMICAL SOC
DOI: 10.1021/la501337c
关键词
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资金
- Ministerio de Economia y Competitividad of Spain [CTQ2011-22436]
- Xunta de Galicia [2007/085]
- FCT (Portugal) [SFRH/BD/43836/2008]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/43836/2008] Funding Source: FCT
The inclusion binding manners of bolaform surfactants of type CnR62+ 2Br(-) with different spacer lengths (n = 6, 12) and terminal headgroup volumes (R = methyl, ethyl) by p-sulfonatocalix[4]arene were studied. The combination of ITC parameters (binding constants and complexation enthalpy and entropy) and NMR chemical shifts and NOE cross-peaks obtained upon complexation allows us to propose different binding modes. The results point out that the spacer length has an influence on the binding stoichiometry. The bolaforms with larger spacer lengths between polar head groups enable the formation of 2:1 complexes in addition to 1:1, while with the shorter spacer they form only 1:1 complexes. On the other hand, the formation of 1:1 complexes is not affected by the headgroup volume or the spacer length of the bolaform. Unexpectedly, a complex binding mode was observed where both positive charged terminal groups of the bolaform are accommodated in the cavity of the calixarene. The inclusion of both terminal groups of the guests can be related to its own structure but also evidence the high flexibility of the calixarene.
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