4.6 Article

Spinel CuCo2O4 Nanoparticles Supported on N-Doped Reduced Graphene Oxide: A Highly Active and Stable Hybrid Electrocatalyst for the Oxygen Reduction Reaction

期刊

LANGMUIR
卷 29, 期 43, 页码 13146-13151

出版社

AMER CHEMICAL SOC
DOI: 10.1021/la4031014

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资金

  1. National Natural Science Foundation of China [21175129]
  2. National Basic Research Program of China [2011CB935800]
  3. Scientific and Technological Development Plan Project of Jilin Province [20100534, 20110448]

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In this Letter, for the first time, we demonstrated the preparation of a highly efficient electrocatalyst, spinel CuCo2O4 nanoparticles supported on N-doped reduced graphene oxide (CuCo2O4/N-rGO), for an oxygen reduction reaction (ORR) under alkaline media. The hybrid exhibits higher ORR catalytic activity than CuCo2O4 or N-rGO alone, the physical mixture of CuCo2O4 nanoparticles and N-rGO, and Co3O4/N-rGO. Moreover, such a hybrid affords superior durability to the commercial Pt/C catalyst.

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