期刊
LANGMUIR
卷 28, 期 31, 页码 11291-11301出版社
AMER CHEMICAL SOC
DOI: 10.1021/la301505e
关键词
-
资金
- Fonds National Suisse de la Recherche Scientifique [200020-124393]
- NCCR MUST
- University of Geneva
Liquid/liquid interfaces play a crucial role in numerous areas of science. However, direct spectroscopic access to this thin (similar to 1 nm) region is not possible with conventional optical methods. After a brief review of the most used techniques to perform interfacial optical spectroscopy, we will focus on time-resolved surface second harmonic generation, which allows the measurement of the excited-state dynamics of probe molecules at interfaces. By comparing these dynamics with those measured in bulk solutions, precious information on the properties of the interfacial region can be obtained. To illustrate this, several studies performed in our group will be presented.
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