期刊
LANGMUIR
卷 26, 期 17, 页码 13747-13750出版社
AMER CHEMICAL SOC
DOI: 10.1021/la101982c
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资金
- U.S. Department of Energy, Division of Materials Science through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign [DE-FG02-07ER46471]
- U.S. Department of Energy [DE-FG02-07ER46471, DE-FG02-07ER46453]
Methods are presented to synthesize suspensions of chemically and shape anisotropic colloids on submicrometer length scales. Particles are synthesized through seeded emulsion polymerization where a weakly cross-linked seed is swollen with monomer that phase separates at the reaction temperature resulting in a protrusion. The final particles can be considered to be composed of interpenetrating spheres. pH-sensitive anisotropy is created through the use of different surface coatings on each of the interpenetrating spheres. Dark-field imaging, dynamic light scattering, and scanning electron microscopy are used to characterize the particles.
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