期刊
LANGMUIR
卷 26, 期 20, 页码 16141-16149出版社
AMER CHEMICAL SOC
DOI: 10.1021/la1029905
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资金
- Department of Science and Technology, New Delhi [SP/SI/OC-11/2004]
- Jawaharlal Nehru Centre for Advance Scientific Research, Bangalore
- CSIR
- Academy of Finland [123801]
- Academy of Finland (AKA) [123801, 123801] Funding Source: Academy of Finland (AKA)
This Article addresses the formation of chiral supramolecular structures in the organogels derived from chiral organogelator 1R (or 2R), and its mixtures with its enantiomer (1S) and achiral analogue 3 by extensive circular dichroism (CD) spectroscopic measurements. Morphological analysis by atomic force microscopy (AFM) and scanning electron microscopy (SEM) were complemented by the measurements of their bulk properties by thermal stability and rheological studies. Specific molecular recognition events (1/3 vs 2/3) and solvent effects (isooctane vs dodecane) were found to be critical in the formation of chiral aggregates. Theoretical studies were also carried out to understand the interactions responsible for the formation of the superstructures.
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