Effective Purification of Single-Walled Carbon Nanotubes with Reversible Noncovalent Functionalization

An effective purification method for single-walled carbon nanotubes (SWNTs) based on a combination of oxidative acid treatment and reversible noncovalent functionalization with 1-pyreneacetic acid is reported. The functionalization was selective toward the nanotubes, allowing a nearly complete removal of residual metal catalysts and carbonaceous impurities. The resulting highly pure SWNTs remained solvent-dispersible, a valuable feature to potential applications that require solvent-based processing. The functionalization agent could be recovered quantitatively and reused. Effects of the purification process on the composition and properties of the nanotube sample were evaluated.