期刊
LANGMUIR
卷 25, 期 24, 页码 14002-14006出版社
AMER CHEMICAL SOC
DOI: 10.1021/la902739q
关键词
-
资金
- National Science Foundation [DMR-0820484]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [820484] Funding Source: National Science Foundation
Self-assembled monolayers (SAMs) were shown to induce very specific oriented growth of simple organic and inorganic crystals, Here we present a detailed study of the mechanism by which SAMs control the oriented nucleation by examining it more complex case of crystallization of bifunctional organic molecules. Malonic and succinic acids were grown on the SAMs of HS(CH2)(10)CO2H and HS(CH2)(11)CO2H supported on gold films. Each SAM induced it very controlled, specific orientation of the crystals. The preferred nucleating planes always exhibited an alignment of one of the carboxylic acid groups in the molecules of the growing crystal with the carboxylic acid groups on the surface of the SAMs. These results suggest that the translation of the structural information through the interface occurs by stereochemical registry such that the functional groups in the SAM play the role of an oriented surrogate layer for the nucleating crystal. These findings are very important to the understanding of the underlying principles by which various organic surfaces-and most probably also biological templates-control the crystallization process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据