期刊
LANGMUIR
卷 25, 期 19, 页码 11232-11235出版社
AMER CHEMICAL SOC
DOI: 10.1021/la9022807
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资金
- INSU/ANR ECCO ECODYN
- Div Of Biological Infrastructure
- Direct For Biological Sciences [830093] Funding Source: National Science Foundation
The nature Of fullerene-water interactions and the role that they play in the fate Of C-60 in aqueous systems is poorly understood. This work provides spectroscopic evidence for the Surface hydroxylation of the initially hydrophobic C-60 molecule when immersed in water. This mechanism appears to be the basis for stabilizing the hydrophilic nC(60) aggregates in suspension. It is remarkable that such a chemical transformation and dispersion are achieved under mild conditions that are readily produced in an aquatic environment. This acquired affinity for water is likely to play a subsequent role in the reactivity, mobility, and bioavailability Of fullerenes in aqueous media.
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