期刊
LANGMUIR
卷 24, 期 17, 页码 9763-9766出版社
AMER CHEMICAL SOC
DOI: 10.1021/la8011684
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-
资金
- Lawrence Livermore National Laboratory [DE-AC52-07NA27344]
- DOE Office of Energy Efficiency and Renewable Energy
We report the synthesis and characterization for the first examples of monolithic low-density carbon aerogel (CA) nanocomposites containing double-walled carbon nanotubes. The CA nancomposites were prepared by the sol-gel polymerization of resorcinol and formaldehyde in an aqueous surfactant-stabilized suspension of double-walled carbon nanotubes (DWNTs). The composite hydrogels were then dried with supercritical CO2 and subsequently carbonized under an inert atmosphere to yield monolithic CA structures containing uniform dispersions of DWNTs. The microstructures and electrical conductivities of these CA nanocomposites were evaluated for different DWNT loadings. These materials exhibited high BET surface areas (>500 m(2)/g) and enhanced electrical conductivities relative to pristine CAs. The details of these results are discussed in comparison with theory and literature.
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