期刊
LAB ON A CHIP
卷 12, 期 8, 页码 1431-1433出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2lc21195e
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- Eni S.p.A. under Eni-MIT Solar Frontiers Center
- National Science Foundation
We report on the design of a microfluidic electrochemical cell with a true Ag/AgCl reference electrode that does not rely on a physical barrier or salt bridge, but instead takes advantage of slow diffusion times in micro-channels. The device concept is demonstrated in PDMS using the Ir+IV/Ir+III redox couple as an example. A scaling analysis provides limits of operation for the device.
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