期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 32, 期 1, 页码 168-177出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-014-0200-6
关键词
Molar Excess Volume; Partial Molar Volume; 1-Propanol; Aromatic Hydrocarbon; Graph Theoretical Approach; Prigogine-Flory-Patterson Theory
资金
- University Grant Commission, New Delhi
Excess molar volumes (V (m) (E) ) have been measured at 303.15 K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using V-shape dilatometer. The V (m) (E) values, for an equimolar composition, vary in the order: benzene > toluenem-xylene > o-xylene > p-xylene. The V (m) (E) data have been used to calculate partial molar volumes, excess partial molar volumes, and apparent molar volumes of 1-propanol and aromatic hydrocarbons over the entire range of composition. The excess volume data have also been interpreted in terms of graph-theoretical approach and Prigogine-Flory-Patterson theory (PFP). While PFP theory fails to predict the V (m) (E) values for systems with s-shaped V (m) (E) versus x(1) graph, the V (m) (E) values calculated by graph theory compare reasonably well with the corresponding experimental values. This graph theory analysis has further yielded information about the state of aggregation of pure components as well as of the mixtures.
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