期刊
KINETICS AND CATALYSIS
卷 51, 期 4, 页码 573-578出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S0023158410040178
关键词
-
资金
- Polish Scientific Research Council [1357/t09/2005/29]
It was studied the influence of gold addition on physico-chemical properties and catalytic activity of bimetallic Ni-Au/Al2O3 catalyst in partial oxidation of methane (POM). The reduction behavior in hydrogen, XRD crystal structure, XPS spectra and POM catalytic activity were investigated. The reduction of Ni-Au catalyst is a prerequisite condition to catalyze POM reaction. The formation of Ni-Au alloy during high temperature reduction in hydrogen and also in the conditions of POM reaction was experimentally proved. The addition of gold to Ni/Al2O3 system improves catalyst stability and activity in POM reaction.
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